Amphiphiles at Interfaces by John Texter

By John Texter

The topic of this quantity is restricted in that it addresses amphiphiles at liquid/air, liquid/liquid, and liquid/solid interfaces, with litte awareness paid to vapor/solid interfaces. This quantity will serve to summarize our present knowing of interfacial constitution on the molecular point in those platforms, and the relation of this constitution to chemical and physicochemical phenomena.

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Gingell D, Todd I, Parsegian VA (1977) Nature 268:76%769 5. Yaguzhinsky LS, Boguslavsky LI, Volkov AG, Rakhmaninova AB (1975) Nature 259:494-496 6. Faraday M (1857) Philos Trans R Soc London 147:145-181 7. Volkov AG, Lozhkin BT, Boguslavsky LI (1975) Doklady Akad Nauk SSSR 220:120%1210 8. Bell RP (1928) J Phys Chem 32:88~893 9. Boguslavsky LI, Kondrashin AA, Kozlov IA, Metelsky ST, Skulachev VP, Volkov AG (1975) FEBS Lett 50:223-226 10. G. W. Deamer Interfacial redox chemistry 11. Kakiuchi T (1996) In: Volkov AG, 22.

5, the methyl carbon atom is practically inaccessible to water. To describe directly the orientation of th~ hydrocarbon chain with respect to the interface we define an end-to-end vector pointing from the methylene carbon atom adjacent to the hydroxyl group, to the methyl carbon atom. Then, we calculate the probability distribution function, P(O), of finding the angle 0, formed between this vector and the normal to the interface directed from hexane to water. P(0) is normalized to describe the probability in the same solid angle for all values of 0.

Relationship between interfacial activity and the mechanism of anesthetic action i0-I According to the Meyer-Overton hypothesis [14, 15], the anesthetic potency of anesthetic compounds is proportional to their solubilities in a non-polar phase, similar to the interior of the neuronal membrane. The remarkable accuracy of this relationship for all clinical and many other anesthetics led to its broader interpretation that anesthetics act inside the neuronal membrane [36].

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